252913
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252913
Aldrich
5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride
| CAS Number: | 36965-71-6 |
| Linear Formula: | C44H8ClF20FeN4 |
| Molecular Weight: | 1063.83 |
| MDL number: | MFCD00012151 |
| PubChem Substance ID: | 24855248 |
Description
| Features and Benefits | Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.4,5,6 |
| Preferred catalyst in catalytic oxygenation reactions.7,8 | |
| Packaging | 100 mg in glass btl |
| Application | Catalyst for epoxidations with peroxides,1 oxidative decarbonylations,2 and aliphatic hydroxylations.3 |
Properties
| UV absorption | λmax 415 nm |
| λmax 498 nm (2nd) |
Safety
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
References
| Cited Reference | 1. J. Am. Chem. Soc. 115, 2775, (1993) |
| 2. Tetrahedron Lett. 33, 4949, (1992) | |
| 3. J. Am. Chem. Soc. 114, 1308, (1992) | |
| 4. J. Am. Chem. Soc. 115, 2775, (1993) | |
| 5. Tetrahedron Lett. 33, 4949, (1992) | |
| 6. J. Am. Chem. Soc. 114, 1308, (1992) | |
| 7. Lee, K.A.; Nam, W. J. Am. Chem. Soc. 119, 1916, (1997) | |
| 8. Kamaraj, K.; Bandyopadhyay, D. J. Am. Chem. Soc. 119, 8099, (1997) | |
| reference | Corp MSDS 1 (2), 3286:A / FT-IR 2 (3), 3432:A / FT-IR 1 (2), 579:C / RegBook 1 (2), 2317:C / Structure Index 1, 363:B:3 |
